Recent Advances In Multifunctional Perovskite Materials

This book summarizes current advances in the field of multifunctional perovskite materials, including information on their synthesis, characterization, and properties as well as their use in the fabrication of devices and applications. Chapters address such topics as the physiochemical properties of various perovskite materials, advances in perovskites for solar cells, and multifunctional materials and their numerous applications.

Perovskite is a well-known structure with the chemical formula ABX3, where A and B are cations coordinated with 12 and 6 anions, respectively, and X is an anion. When a halogen anion is used, the monovalent A and divalent B cations can be stabilized with respect to a tolerance factor ranging from ~0.8 to 1. Since the first report on ~10% efficiency and long-term stability of solid-state perovskite solar cells (PSCs) in 2012 and two subsequent seed reports on perovskite-sensitized solar cells in 2009 and 2011, PSCs have received increasing attention. The power conversion efficiency of PSCs was certified to be more than 25% in 2020, surpassing thin-film solar cell technologies. Methylammonium or formamidinium organic ion–based lead iodide perovskite has been used for high-efficiency PSCs. The first report on solid-state PSCs triggered perovskite photovoltaics, leading to more than 23,000 publications as of October 2021. In addition, halide perovskite has shown excellent performance when applied to light-emitting diodes (LEDs), photodetectors, and resistive memory, indicating that halide perovskite is multifunctional. This book explains the electro-optical and ferroelectric properties of perovskite and details the recent progress in scalable and tandem PSCs as well as perovskite LEDs and resistive memory. It is a useful textbook and self-help study guide for advanced undergraduate- and graduate-level students of materials science and engineering, chemistry, chemical engineering, and nanotechnology; for researchers in photovoltaics, LEDs, resistive memory, and perovskite-related opto-electronics; and for general readers who wish to gain knowledge about halide perovskite.

Advanced Lightweight Multifunctional Materials presents the current state-of-the-art on multifunctional materials research, focusing on different morphologies and their preparation and applications. The book emphasizes recent advances on these types of materials as well as their application. Chapters cover porous multifunctional materials, thermochromic and thermoelectric materials, shape memory materials, piezoelectric multifunctional materials, electrochromic and electrorheological, soft materials, magnetic and photochromic materials, and more. The book will be a valuable reference resource for academic researchers and industrial engineers working in the design and manufacture of multifunctional materials, composites and nanocomposites. Provides detailed information on design, modeling and structural applications Focuses on characteristics, processing, design and applications Discusses the main types of lightweight multifunctional materials and processing techniques, as well as the physico-chemical insights that can lead to improved performance

In this book we explore new approaches to understanding the physical and chemical properties of emergent complex functional materials, revealing a close relationship between their structures and properties at the molecular level. The primary focus of this book is on the ability to synthesize materials with a controlled chemical composition, a crystallographic structure, and a well-defined morphology. Special attention is also given to the interplay of theory, simulation and experimental results, in order to interconnect theoretical knowledge and experimental approaches, which can reveal new scientific and technological directions in several fields, expanding the versatility to yield a variety of new complex materials with desirable applications and functions. Some of the challenges and opportunities in this field are also discussed, targeting the development of new emergent complex functional materials with tailored properties to solve problems related to renewable energy, health, and environmental sustainability. A more fundamental understanding of the physical and chemical properties of new emergent complex functional materials is essential to achieving more substantial progress in a number of technological fields. With this goal in mind, the editors invited acknowledged specialists to contribute chapters covering a broad range of disciplines.

Metal oxide nanoparticles exhibit potential applications in energy and environmental fields, such as solar cells, fuel cells, hydrogen energy, and energy storage devices. This book covers all points from synthesis, properties, and applications of transition metal oxide nanoparticle materials in energy storage and conversion devices. Aimed at graduate-level students and researchers associated with the energy and environment sector, this book addresses the application of nontoxic and environmentally friendly metal oxide materials for a clean environment and deals with synthesis properties and application metal oxides materials for energy conversion, energy storage, and hydrogen generation.

Conventional building skins are constructed as static structures upon the typical design conditions in terms of external climate and internal occupant activities. This generates dissociation between the envelope structure and its environment. With the emerging advanced materials, such as chromic-based materials, spectrally selective coatings, and transparent photovoltaic, more dynamic and smarter building skins are now achievable and constructible. This book updates readers on the key areas of smart building skins embodied in the novel advanced materials with unique structures and smart properties that enable multiple functions in energy efficiency, solar harvesting, and environmental greenness. It synergistically integrates the topics and knowledge of material design and experimental studies, theoretical analyses of building energy-saving mechanisms and solar energy utilization, and new design methodologies and processes taking advanced materials into account at different scales - from nano to the macroscale.

PEROVSKITE MATERIALS FOR ENERGY AND ENVIRONMENTAL APPLICATIONS The book provides a state-of-the-art summary and discussion about the recent progress in the development and engineering of perovskite solar cells materials along with the future directions it might take. Among all 3rd generation solar cells, perovskite solar cells have recently been attracting much attention and have also emerged as a hot research area of competing materials for silicon PV due to their easy fabrication, long charge-carrier lifetime, low binding energy, low defect density, and low cost. This book focuses primarily on the perovskite structures and utilizes them in modern technologies of photovoltaics and environmental applications. It will be unique in terms of the use of perovskite structures in solar cell applications. This book also discusses the type of perovskites, their synthetic approach, and environmental and solar cell applications. The book also covers how perovskite solar cells originated and the recent advances in perovskite solar cells. The reader will find in this book a lucid account that: Introduces the history of perovskite materials. Explores perovskite materials for energy conversion and environmental-related applications. Covers perovskite light absorber materials for the fabrication of high-performance perovskite solar cells. Describes the device architectures and physics of perovskite solar cells. Discusses the role of perovskite absorber, electron transport, and hole transport materials layers. Audience The book is essential reading for all those in the photovoltaic community, including materials scientists, surface physicists, surface chemists, solid-state physicists, solid-state chemists, and electrical engineers.