Rubber Technology

About ten years after the publication of the Second Edition (1973), it became apparent that it was time for an up-date of this book. This was especially true in this case, since the subject matter has traditionally dealt mainly with the structure, properties, and technology of the various elastomers used in industry, and these are bound to undergo significant changes over the period of a decade. In revising the contents of this volume, it was thought best to keep the orig inal format. Hence the first five chapters discuss the same general subject matter as before. The chapters dealing with natural rubber and the synthetic elastomers are up-dated, and an entirely new chapter has been added on the thermoplastic elastomers, which have, of course, grown tremendously in importance. Another innovation is the addition of a new chapter, "Miscellaneous Elastomers," to take care of "old" elastomers, e.g., polysulfides, which have decreased some what in importance, as well as to introduce some of the newly-developed syn thetic rubbers which have not yet reached high production levels. The editor wishes to express his sincere appreciation to all the contributors, without whose close cooperation this task would have been impossible. He would especially like to acknowledge the invaluable assistance of Dr. Howard Stephens in the planning of this book, and for his suggestion of suitable authors.

Rapra Technology is the leading independent international organisation with over 80 years of experience providing technology, information and consultancy on all aspects of rubbers and plastics. The company has extensive processing, analytical and testing laboratory facilities and expertise, and produces a range of engineering and data management software products, and computerised knowledge-based systems. Rapra also publishes books, technical journals, reports, technological and business surveys, conference proceedings and trade directories. These publishing activities are supported by an Information Centre which maintains and develops the world's most comprehensive database of commercial and technical information on rubbers and plastics. Book jacket.

The core content of this book is derived from the author’s experience as a Senior Technocrat, associated with the rubber industry in the aspects of Production, R&D and new plant erection and commissioning. This book is dedicated to a variety of Rubber Starting Point Formulations that could be very useful for the rubber industry. The rubber industry is an important resource-based industry in India. Over many decades, the rubber industry has witnessed steady and strong growth. Rubber can be processed in many ways to manufacture a wide range of products. This book provides the starting point formulations that cover the manufacturing processes of rubber products such as calendaring, extrusion and molding. Thus, the book is very useful for new entrepreneurs, existing units, technical institutions and technocrats. These formulations are based on General Compounding Principles and properties such as Tensile Strength, Tear Resistance, The Crescent Tear Test, The Hardness of Rubber, Abrasion Resistance, Flex Cracking Resistance, Resilience, Heat Build-up, and Temperature Resistance. The formulations are aimed at products like Retreading Materials, Conveyor Belting, Transmission Belting and Hose, Footwear, Rubber Roller, Medical Applications, O rings and Seals, Rubber Blends and Manufacture of Latex Products.

The 3rd edition of The Science and Technology of Rubber provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling. · Explores new applications of rubber within the tire industry, from new filler materials to “green tires (a tire that has yet to undergo curing and vulcanization). · 30% of the material has been revised from the previous edition with the addition of 20% new material, including a chapter on the environment. · A mixture of theory, experiments, and practical procedures will offer value to students, practitioners, and research & development departments in industry.

This volume, the fourth in a series which began in 1979, covers a greater variety of subjects than any previous single volume. The basis of selection has been topical interest; hence the tailor-making of polymers to develop specific properties, methods of improving com pound processability and the use of rubbers in the oil industry are featured alongside a discussion of safety aspects. We have again sought the cooperation of the foremost authorities on the chosen subjects and have been delighted at the response which has yielded a list of authors of international repute. A. w. K. S. L. CONTENTS Preface v List of Contributors ix 1. Recent Developments in Synthetic Rubbers by Anionic Polymerization 1 I. G. HARGIS, R. A. LIVIGNI and S. L. AGGARWAL 2. Advances in Nitrile Rubber (NBR) 57 P. W. MILNER 3. Epoxidized Natural Rubber. 87 C. S. L. BAKER and I. R. GELLING 4. Process Aids and Plasticizers . 119 B. G. CROWTHER 5. A Review of Elastomers Used for Oilfield Sealing Environments . 159 W. N. K. REVOLTA and G. C. SWEET 6. Using Modern Mill Room Equipment . 193 H. ELLWOOD 7. Quality Requirements and Rubber Mixing . 221 P. S. JOHNSON 8. Health and Safety . . 253 B. G. WILLOUGHBY Index . 307 vii LIST OF CONTRIBUTORS s. L. AGGARWAL Gen Corp , Research Division, 2990 Gilchrist Road, Akron, Ohio 44305, USA C. S. L. BAKER Malaysian Rubber Producers' Research Association, Tun Abdul Razak Laboratory, Brickendonbury, Hertford SG13 8NL, UK B. G.

This review has been written as a practical guide to rubber injection moulding. Many injection moulding processes produce rejects or scrap, because they depend on a b257 of variables. To eliminate waste it is necessary to learn how to recognise the variables that cause problems, and then experiment to understand their interdependence. This can be developed to a fine art and lead towards 'right first time' processing, the commercial ideal. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database gives useful references for further reading.