Stereodirected Synthesis With Organoboranes
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Stereodirected Synthesis with Organoboranes
Author | : Donald S. Matteson |
Publsiher | : Springer Science & Business Media |
Total Pages | : 417 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 9783642797095 |
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This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
Organoboranes in Organic Synthesis
Author | : Gordon M. L. Cragg |
Publsiher | : Unknown |
Total Pages | : 448 |
Release | : 1973 |
Genre | : Science |
ISBN | : UOM:39015016063615 |
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Synthesis of Functionalized Organoboron Compounds Through Copper I Catalysis
Author | : Koji Kubota |
Publsiher | : Springer |
Total Pages | : 213 |
Release | : 2017-06-27 |
Genre | : Science |
ISBN | : 9789811049354 |
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This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, and efficient method for their preparation in the past several years. However, the synthesis of functionalized organoboron compounds remains a challenging issue because known reactions often require the use of highly reactive organometallic carbon nucleophiles. This book focuses on conceptually new, formal nucleophilic copper(I)-catalyzed borylation reactions with diboron compounds that show high selectivity and excellent functional group compatibility. Theoretical studies based on density functional theory calculations to understand the reaction mechanisms have also been described. Advances in this novel borylation chemistry will allow the rapid and efficient synthesis of complex molecules with potentially interesting properties in combination with the boron functionalization process.
Modern Organic Synthesis
Author | : George S. Zweifel,Michael H. Nantz,Peter Somfai |
Publsiher | : John Wiley & Sons |
Total Pages | : 416 |
Release | : 2017-03-09 |
Genre | : Science |
ISBN | : 9781119086727 |
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This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents
Part B Reactions and Synthesis
Author | : Francis A. Carey,Richard J. Sundberg |
Publsiher | : Springer |
Total Pages | : 972 |
Release | : 2013-11-27 |
Genre | : Science |
ISBN | : 9783662395103 |
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Organoboranes for Syntheses
Author | : P. Veeraraghavan Ramachandran |
Publsiher | : Unknown |
Total Pages | : 272 |
Release | : 2001 |
Genre | : Medical |
ISBN | : UOM:39015049703856 |
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This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction, aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis, boron catalysts for stereoselective transformations, heterocyclic synthesis and novel borohydride reagents.
Copper Catalyzed Asymmetric Synthesis
Author | : Alexandre Alexakis,Norbert Krause,Simon Woodward |
Publsiher | : John Wiley & Sons |
Total Pages | : 467 |
Release | : 2013-12-30 |
Genre | : Science |
ISBN | : 9783527664597 |
Download Copper Catalyzed Asymmetric Synthesis Book in PDF, Epub and Kindle
This book reflects the increasing interest among the chemical synthetic community in the area of asymmetric copper-catalyzed reactions, and introduces readers to the latest, most significant developments in the field. The contents are organized according to reaction type and cover mechanistic and spectroscopic aspects as well as applications in the synthesis of natural products. A whole chapter is devoted to understanding how primary organometallics interact with copper to provide selective catalysts for allylic substitution and conjugate addition, both of which are treated in separate chapters. Another is devoted to the variety of substrates and experimental protocols, while an entire chapter covers the use on non-carbon nucleophiles. Other chapters deal with less-known reactions, such as carbometallation or the additions to imines and related systems, while the more established reactions cyclopropanation and aziridination as well as the use of copper (II) Lewis acids are warranted their own special chapters. Two further chapters concern the processes involved, as determined by mechanistic studies. Finally, a whole chapter is devoted to the synthetic applications. This is essential reading for researchers at academic institutions and professionals at pharmaceutical or agrochemical companies.
Lithium Compounds in Organic Synthesis
Author | : Renzo Luisi,Vito Capriati |
Publsiher | : John Wiley & Sons |
Total Pages | : 576 |
Release | : 2014-03-11 |
Genre | : Science |
ISBN | : 9783527667536 |
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This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field. Part I covers computational and spectroscopic aspects as well as structure-reactivity relationships of organolithiums, whereas Part II deals with new lithium-based synthetic methodologies as well as novel synthetic applications of functionalized lithium compounds. A useful resource for newcomers and active researchers involved in organic synthesis, whether working in academia or industry!