Use Of Humic Substances To Remediate Polluted Environments

Effective remediation of polluted environments is a priority in both Eastern and Western countries. In the U.S. and Europe, remediation costs generally exceed the net economic value of the land. As a result, scientists and engineers on both sides of the Atlantic have aggressively tried to develop novel technologies to meet regulatory standards at a fraction of the costs. In situ remediation shows considerable promise from both technical and economic perspectives. In situ technologies that deploy natural attenuating agents such as humic substances (HS) may be even more cost effective. Numerous studies have shown humics capable of altering both the chemical and the physical speciation of the ecotoxicants and in turn attenuate potential adverse environmental repercussions. Furthermore, the reserves of inexpensive humic materials are immense. Which suggests HS portend great promise as inexpensive amendments to mitigate the environmental impacts of ecotoxicants and as active agents in remediation. To elucidate emerging concepts of humics-based remediation technologies, we organized the NATO Advanced Research Workshop (ARW), entitled "Use of humates to remediate polluted environments: from theory to practice", held on September 23-29, 2002 in Zvenigorod, Russia (see the web-site http://www.mgumus.chem.msu.ru/arw).

Effective remediation of polluted environments is a priority in both Eastern and Western countries. In the U.S. and Europe, remediation costs generally exceed the net economic value of the land. As a result, scientists and engineers on both sides of the Atlantic have aggressively tried to develop novel technologies to meet regulatory standards at a fraction of the costs. In situ remediation shows considerable promise from both technical and economic perspectives. In situ technologies that deploy natural attenuating agents such as humic substances (HS) may be even more cost effective. Numerous studies have shown humics capable of altering both the chemical and the physical speciation of the ecotoxicants and in turn attenuate potential adverse environmental repercussions. Furthermore, the reserves of inexpensive humic materials are immense. Which suggests HS portend great promise as inexpensive amendments to mitigate the environmental impacts of ecotoxicants and as active agents in remediation. To elucidate emerging concepts of humics-based remediation technologies, we organized the NATO Advanced Research Workshop (ARW), entitled "Use of humates to remediate polluted environments: from theory to practice", held on September 23-29, 2002 in Zvenigorod, Russia (see the web-site http://www.mgumus.chem.msu.ru/arw).

This is the first book aimed at the development of a common language among scientists working in the field of humic research and environmental engineers specialized in remediation technologies. In pursuing this goal, the engineer is provided with sufficient information on the basics and state of the art of humic research pertinent to remediation. For the interested scientist, this text provides sufficient information on the methods, needs, and limitations of existing remediation technologies, and on the latest developments in applied humic research. A novel approach is undertaken to categorizing the interactions encountered between humics, ecotoxicants, and living organisms in a polluted environment in the context of remediation chemistry. The volume pays particular attention to in situ remediation as the most viable option for the application of humics. The content of this book is of interest to scientists and engineers.

Despite having been published about two years ago for the first time, the continuous demand for this book encouraged me to prepare this revised and enlarged edition. Many parts of the text have been rewritten, type errors traced and corrected, and the bibliography largely modified to include many of the references published about the subject of soil pollution in the previous ten years. I should like to express my thanks to the staff of Springer-Verlag, Heidelberg, for their cooperative efforts in preparing this edition. I also would like to thank Mr. Michael Sidwell (B.A.) for the extreme but characteristic care with which he read and revised the proofs. I hope that, in this new edition, the book may continue to serve the needs of students and professionals alike interested in the subject of soil pollution. Ibrahim A. Mirsal Preface to the First Edition Whoever has enjoyed following the legendary duel between the Egyptian Pharaoh and his magicians (Alchemists) on one side, and Moses and his brother Aaron on the other, as is vividly narrated in the Bible, must have realised that people (at least those living at, or near the eternal battlefields of the Middle East) have always had knowledge about the terrible consequences of soil pollution by chemicals. This knowledge must have existed long before Moses and his Pharaoh. Nobody knows when people became aware of this, yet it must have been born in very early times, reaching back to the dawn of human conscious.

This book details the state-of-the art in early warning monitoring of anthropogenic pollution of soil and water. It is unique with regard to its complex, multidisciplinary, mechanistic approach. Top scientists establish links and strengthen weak connections between specific fields in biology, microbiology, chemistry, biochemistry, toxicology, sensoristics, soil science and hydrogeology.

Why do some contaminants remain in soils indefinitely? How much of a threat do they pose to human health or the environment? The need for effective and economic site decontamination arises daily. Geoenvironmental Engineering: Contaminated Soils, Pollutant Fate, and Mitigation discusses why soils remain contaminated, focusing on the development of the factors, properties, characteristics, and parameters of soils and individual contaminants. Subjects covered include the basic properties of soils affecting accumulation of contaminants, long-term retention of contaminants and their fate, including the development of intermediate products. The author emphasizes the factors, interactions, and mechanisms important in the bonding and partitioning process. He provides the groundwork for determining the fate of pollutants in soils and sediments and their mitigation. Geoenvironmental Engineering: Contaminated Soils, Pollutant Fate, and Mitigation focuses on why soils and sediments remain contaminated, not how they became contaminated in the first place. You will understand why specific contaminants remain in soils and sediments, how much of a threat they pose to human health and the environment, and what steps to take for mitigation. With this information you can determine the extent of the contamination of soils and sediments, how long they will remain a threat, and what methods to use for their remediation.

Newly developed and innovative methods are mentioned and outlined so that the book can be used as a source of information for scientists and professionals specialised in the treatment of soils as well as for students in courses of environmental studies. The book offers a short, compressed overview of the important features of this subject and can be used as a reference book of the state of the art. The appendix offers the interested reader a detailed survey of materials, test methods and apparatuses as well as a description of analytical directions and processes.

In the continuing fight against organic environmental xenobiotics, the initial success attributed to bioremediation has paled, in part due to the low availability of xenobiotics entrapped within a soil or sediment matrix. This has generated a very significant wave of interest in the bioavailability issue. However, much experimental evidence is puzzling or contradictory, mechanistic theories are embryonic, and implications for the practice of bioremediation or concerning the natural fate of xenobiotics are still tentative. The debate in Europe and the USA is vigorous. Eastern Europe, following the liberalisation of the economy and political life, is evolving in a similar direction. In many cases, however, limited access to literature sources, severe language barriers, and the lack of a strong pluridisciplinary tradition are hampering the adoption of state of the art techniques. Originally intended to allow scientists in East European countries to become acquainted with the key aspects of the bioavailability debate that is unfolding in the scientific literature in the West, and with its implications for bioremediation efforts, the present book presents a very complete coverage of the theoretical and practical aspects of the (limited) bioavailability of organic xenobiotics in the environment.