Vegetable Oil Based Polymers

The growing need to find a sustainable, environmentally-friendly replacement for petroleum-based materials is fuelling the development of bio-based polymers from renewable resources. Amongst the most promising of these are vegetable oil-based polymeric materials. Vegetable oil-based polymers provides a comprehensive review of the research in this important field. After an introduction to classification and polymerization, Vegetable oil-based polymers goes on to review the factors involved in polymer biodegradation. The extraction, purification and application of vegetable oils are then explored, along with vegetable oil-based polyesters and poly(ester amide)s, polyurethanes and epoxies. The book then reviews polyamides, polyolefins and vegetable oil-based hyperbranched polymers. It concludes with an analysis of vegetable oil-based polymer composites and polymer nanocomposites. Vegetable oil-based polymers is an indispensable guide for all those involved in the research and development of biopolymers as well as the wide range of industries looking for more sustainable polymer materials. Provides a comprehensive review of recent research in the area of vegetable oil-based polymeric materials Discusses vegetable oils and their derivatives, biodegradable polymers and the fundamentals of polymers Explores the extraction, purification and application of vegetable oils, along with vegetable oil-based polyesters and poly(ester amide)s, polyurethanes and epoxies

The purpose of this monograph is to provide a thorough outlook on the topic related to the synthesis and characterization of original macromolecular materials derived from plant oils, an important part of the broader steadily growing discipline of polymers from renewable resources. The interest in vegetable oils as sources of biodiesel and materials has witnessed a remarkable growth of scientific and industrial interest since the beginning of the third millennium responding to the pressing drive to implement sustainability in the energy and materials sectors. The book highlights the most relevant strategies being pursued to elaborate polymers derived from a variety of common oils, by direct activation or through chemical modifications yielding novel monomers. Because glycerol is the main byproduct of biodiesel production, it is treated here as the other logical source of macromolecular synthesis. Each of the different approaches is illustrated by an introductory layout of the underlying chemical mechanisms, followed by examples of notable achievements in terms of the properties and potential applications of the ensuing materials, which span a wide range of structures and performances. In particular, original pathways involving click-chemistry reactions as thiol-ene and Diels-Alder couplings and metathesis polymerizations are discussed and shown to reflect the involvement of a growing number of research programs worldwide. It is important to underline that the book is not a scientific review covering the details of all relevant literature, but instead a reasoned and well-documented presentation of the state-of-the-art aimed at professionals in the field of polymer science, as well as at both undergraduate and graduate students and, more generally at chemists interested in the rational exploitation of renewable resources.

Vegetable Oil Based Polymers and Their Surface Applications presents detailed coverage of principles, preparation methods and novel surface uses of vegetable oil based polymers. This comprehensive, state-of-the-art book follows the journey of vegetable oils from seeds to surfaces in a range of advanced applications. Opening chapters discuss theory, principles and characterization techniques while other sections present concepts on the preparation of different polymer types based on vegetable oil. The final section of the book provides extensive coverage of applications, enabling the preparation of vegetable oil based polymers for a range of products and industries. This is a valuable resource for researchers, scientists, and advanced students in polymer chemistry, surfaces and coatings, natural polymers, materials chemistry, chemical engineering and plastics engineering. In an industrial setting, this book supports R&D professionals, scientists, and engineers interested in developing innovative biobased materials for a range of applications, including automotive and aerospace, packaging, cosmetics, pharmaceuticals, biomedicine and consumer goods. Provides in-depth information on the preparation of vegetable oil-based epoxies, alkyds, polyesteramides, polyetheramides and polyurethanes Explores cutting-edge surface applications of vegetable oil-based polymers in areas such as coatings, packaging, cosmetics and wound dressings Includes other key considerations, including cost benefit analysis, lifecycle assessment and future developments

This book discusses vegetable oil based biolubricants and their applications in the power distribution industry. Vegetable oil based lubricants offer significant advantages over petroleum-based lubricants, including biodegradability, cost-effectiveness, renewability, and lower environmental effects. This book provides a detailed literature survey of modified vegetable oils. It discusses the physical and chemical properties of vegetable oil, and their effects on its applications in tribology. The book discusses additives and enhancements to make vegetable oils suitable for use as lubricating oils and transformer oils in power plants and power distribution grids. The contents of the book will be useful to researchers and professionals as well as policy makers and standards agencies.

Bio-based Plant Oil Polymers and Composites provides engineers and materials scientists a useful framework to help take advantage of the latest research conducted in this rapidly advancing field—enabling them to develop and commercialize their own products quickly and more successfully. Plant oil is one of the most attractive options as a substitute for non-renewable resources in polymers and composites, and is producing materials with very promising thermomechanical properties relative to traditional, petroleum-based polymers. In addition to critical processing and characterization information, the book assists engineers in deciding whether or not they should use a plant oil-based polymer over a petroleum-based polymer, discussing sustainability concerns, biodegradability, associated costs, and recommended applications. The book details the advancements in the development of polymeric materials and composites from plant oils, and provides a critical review of current applications in various fields, including packaging, biomedical, and automotive applications. Also includes the latest progress in developing multifunctional biobased polymers—by increasing thermal conductivity or adding antibacterial properties, for example. Essential coverage of processing, characterization, and the latest research into polymeric materials and composites derived from plant oils (thermoplastics, thermosets, nanocomposites, and fiber reinforced composites) Critically reviews the potential applications of plant oil-based polymers, including sensors, structural parts, medical devices, and automotive interiors Includes the latest developments in multifunctional bio-based polymer composites

Bio-Based Polymers and Composites is the first book systematically describing the green engineering, chemistry and manufacture of biobased polymers and composites derived from plants. This book gives a thorough introduction to bio-based material resources, availability, sustainability, biobased polymer formation, extraction and refining technologies, and the need for integrated research and multi-disciplinary working teams. It provides an in-depth description of adhesives, resins, plastics, and composites derived from plant oils, proteins, starches, and natural fibers in terms of structures, properties, manufacturing, and product performance. This is an excellent book for scientists, engineers, graduate students and industrial researchers in the field of bio-based materials. * First book describing the utilization of crops to make high performance plastics, adhesives, and composites * Interdisciplinary approach to the subject, integrating genetic engineering, plant science, food science, chemistry, physics, nano-technology, and composite manufacturing. * Explains how to make green materials at low cost from soyoil, proteins, starch, natural fibers, recycled newspapers, chicken feathers and waste agricultural by-products.

This brief outlines the most recent advances in the production of polyols and polyurethanes from renewable resources, mainly vegetable oils, lignocellulosic biomass, starch, and protein. The typical processes for the production of polyols from each of the above mentioned feedstocks are introduced and the properties of the resultant polyols and polyurethanes are also discussed.