Electrons In Fluids

Colloque Weyl I was convened in June 1963 at the Catholic University of Lille to commemorate one hundred years of the study of metal-ammonia solutions. This memorable event, which involved a "single-particle excitation", inspired Gerard Lepoutre to assemble an international group of physicists and chemists to discuss the nature of metal-ammonia solutions. Colloque Weyl II, which took 1969, was initiated as a place at Cornell Universtiy, Ithaca, N.Y. in June "cooperative interaction" between M. J. Sienko, J. L. Dye, J. J. Lagowski, G. Lepoutre and J. C. Thompson. That meeting made it clear that Colloque Weyl should be continued in order to promote the fruitful exchange of ideas set in motion at Lille and at Cornell. Colloque Weyl III came into being as the result of a resolution passed at the Cornell meeting, Tel-Aviv University being the suggested site. The Organizing Committee consisted ofE. D. Bergmann, J. Jortner, J. J. Lagowski, G. Lepoutre, U. Schindewolf and M. J. Sienko, reflecting the international and interdisciplinary aspects of the field.

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

This book provides a comprehensive review of the present knowledge and current problems concerning physical-chemical aspects of the behavior of excess electrons in various media. The book's 13 chapters strike a balance between theoretical and experimental accounts and provide in-depth presentations of specific subjects. Among the several topics discussed in this stimulating volume are primary interactions, transport, and relaxation of excess electrons of a few tens of electron-Volts in various solid and liquid materials; energetics and transport properties of electrons after thermalization in non-polar dielectric liquids; quantum simulation methods; and electron solvation in polar liquids and of excess electrons trapped in polar matrices at low temperature. Applications of these concepts are discussed as well, including hot electron transport in silicon dioxide, the fate of excess electrons created in polar dielectric liquids by photoelectrochemical methods or by cathodic generation, and excess electron production and decay in organic microheterogeneous systems. Researchers, instructors, and engineers working in the radiation sciences, condensed-matter physics, chemical physics, biophysics, photochemistry, and the biochemistry of electron transfer and electrochemistry should consider this book to be an invaluable reference resource.

This revised and expanded Third Edition contains 21 chapters summarizing the latest thinking on various technologies relating to metalworking fluid development, laboratory evaluation, metallurgy, industrial application, fluid maintenance, recycling, waste treatment, health, government regulations, and cost/benefit analysis. All chapters of this uniquely comprehensive reference have been thoroughly updated, and two new chapters on rolling of metal flat sheets and nanoparticle lubricants in metalworking have been added. This must-have book for anyone in the field of metalworking includes new information on chemistries of the most common types of metalworking fluids, advances in recycling of metalworking fluids, and the latest government regulations, including EPA standards, the Globally Harmonized System being implemented for safety data sheets, and REACH legislation in Europe.

Ionic liquids have attracted considerable interest in recent years. In this book the bulk and interfacial physico-chemical characteristics of various fluid systems dominated by Coulomb interactions are treated which includes molten salts, ionic liquids as well as metal-molten salt mixtures and expanded fluid metals. Of particular interest is the comparison of the different systems. Topics in the bulk phase concern the microscopic structure, the phase behaviour and critical phenomena, and the metal-nonmetal transition. Interfacial phenomena include wetting transitions, electrowetting, surface freezing, and the electrified ionic liquid/ electrode interface. With regard to the latter 2D and 3D electrochemical phase formation of metals and semi-conductors on the nanometer scale is described for a number of selected examples. The basic concepts and various experimental methods are introduced making the book suitable for both graduate students and researchers interested in Coulombic fluids.

Advances in Electronics and Electron Physics

Modern electronic devices and novel materials often derive their extraordinary properties from the intriguing, complex behavior of large numbers of electrons forming what is known as an electron liquid. This book provides an in-depth introduction to the physics of the interacting electron liquid in a broad variety of systems, including metals, semiconductors, artificial nano-structures, atoms and molecules. One, two and three dimensional systems are treated separately and in parallel. Different phases of the electron liquid, from the Landau Fermi liquid to the Wigner crystal, from the Luttinger liquid to the quantum Hall liquid are extensively discussed. Both static and time-dependent density functional theory are presented in detail. Although the emphasis is on the development of the basic physical ideas and on a critical discussion of the most useful approximations, the formal derivation of the results is highly detailed and based on the simplest, most direct methods.