Humus Chemistry

A reference text focusing on basic organic chemistry and reactions of naturally occurring organic substances in soils. Covers pools of organic matter in soils, transformations, methods of extraction and fractionation. Section two deals primarily with the chemistry of known classes of organic compounds in soils including saccharides, lipids and constituents containing nitrogen, phosphorus and sulfur. Section three is concerned with basic organic chemistry of humic substances, followed by the importance of organic matter associations and interactions. Contains new chapters on NMR spectroscopy, analytical pyrolysis and on chemical structures.

Soil and Environmental Chemistry, Second Edition, presents key aspects of soil chemistry in environmental science, including dose responses, risk characterization, and practical applications of calculations using spreadsheets. The book offers a holistic, practical approach to the application of environmental chemistry to soil science and is designed to equip the reader with the chemistry knowledge and problem-solving skills necessary to validate and interpret data. This updated edition features significantly revised chapters, averaging almost a 50% revision overall, including some reordering of chapters. All new problem sets and solutions are found at the end of each chapter, and linked to a companion site that reflects advances in the field, including expanded coverage of such topics as sample collection, soil moisture, soil carbon cycle models, water chemistry simulation, alkalinity, and redox reactions. There is also additional pedagogy, including key term and real-world scenarios. This book is a must-have reference for researchers and practitioners in environmental and soil sciences, as well as intermediate and advanced students in soil science and/or environmental chemistry. Includes additional pedagogy, such as key terms and real-world scenarios Supplemented by over 100 spreadsheets to migrate readers from calculator-based to spreadsheet-based problem-solving that are directly linked from the text Includes example problems and solutions to enhance understanding Significantly revised chapters link to a companion site that reflects advances in the field, including expanded coverage of such topics as sample collection, soil moisture, soil carbon cycle models, water chemistry simulation, alkalinity, and redox reactions

Despite the large number of papers and books published on soil organic matter (humus), our knowledge of the subject is still very limited, as is our knowledge of humic acid. The author of this book began to study humus at the end of the 1940s and continued until 1984 when he retired from Nagoya University. With the intention of establishing a systematic understanding of soil organic matter, he has compiled facts and a discussion of humus based on his extensive experimental results during the past 40 years. In this book, humic acids are classified into A, B, Rp and P types, based on their optical properties. The elementary composition and other chemical properties of humic acid types are shown to be regularly different from each other. A new method for humus composition analysis applied to various kinds of soils in Japan and several other countries indicates that the diversity of humus compositions of soils is systematically understandable. These findings lead the author to novel theories on the chemical configuration and formation of humic acids and humic substances. Diagenesis of humus under terrestrial conditions is illustrated as to the buried humic horizons of Black soil (Andosol). The book will be useful not only to soil scientists and agronomists but also to geochemists, oceanographers, limnologists, water scientists, biologists and chemists who are dealing with organic matter in terrestrial, aquatic, and sedimentary environments.

Environmental Soil Chemistry illustrates fundamental principles of soil chemistry with respect to environmental reactions between soils and other natural materials and heavy metals, pesticides, industrial contaminants, acid rain, and salts. Timely and comprehensive discussions of applications to real-world environmental concerns are a central focus of this established text. Provides students with both sound contemporary training in the basics of soil chemistry and applications to real-world environmental concerns Timely and comprehensive discussion of important concepts including: sorption/desorption, oxidation-reduction of metals and organics, and effects of acidic deposition and salinity on contaminant reacions Boxed sections focus on sample problems and explanations of key terms and parameters Extensive tables on elemental composition of soils, rocks and sediments, pesticide classes, inorganic minerals, and methods of decontaminating soils Clearly written for all students and professionals in environmental science and environmental engineering as well as soil science

The second edition of The Chemistry of Soils, published in 2008, has been used as a main text in soil-science courses across the world, and the book is widely cited as a reference for researchers in geoscience, agriculture, and ecology. The book introduces soil into its context within geoscience and chemistry, addresses the effects of global climate change on soil, and provides insight into the chemical behavior of pollutants in soils. Since 2008, the field of soil science has developed in three key ways that Sposito addresses in this third edition. For one, research related to the Critical Zone (the material extending downward from vegetation canopy to groundwater) has undergone widespread reorganization as it becomes better understood as a key resource to human life. Secondly, scientists have greatly increased their understanding of how organic matter in soil functions in chemical reactions. Finally, the study of microorganisms as they relate to soil science has significantly expanded. The new edition is still be comprised of twelve chapters, introducing students to the principal components of soil, discussing a wide range of chemical reactions, and surveying important human applications. The chapters also contain completely revised annotated reading lists and problem sets.

The field of humic matter research has undergone drastic changes in concepts and principles since the first edition of Humic Matter in Soil and the Environment: Principles and Controversies was published more than a decade ago. Still the only book of its kind specifically addressing humic acid principles and controversies, the Second Edition presents the newest advances in humic acid science. Eleven new and rewritten chapters replace the original nine, with updated material representing modern humic acid chemistry. This includes the delineation of organic matter, humus, and humic matter. The book begins by considering organic matter as a whole, describing terrestrial and aquatic organic matter. It examines humus as a mixture of humified and nonhumified organic matter, focusing also on the importance of the nonhumified fraction—plant biopolymers in their original or slightly decomposed forms—as raw materials for formation of the humic fraction. The book then presents concepts of humic matter, referred to as humic acid, covering a range of ideas from traditional views of biopolymers to the latest concepts based on micellar, supramolecular, and nanotube chemistry. The author presents the major pathways of humification and discusses humification theories. He also examines the extraction, isolation, and fractionation of humic matter. The book reviews the chemical composition and model structures of humic acids, the chemical and spectroscopic characterization of humic substances, and the electrochemical properties of humic matter. It also addresses the agronomic, environmental, and industrial (including pharmaceutical) importance of humic matter. This revised and updated edition continues the tradition of providing comprehensive coverage of the genesis, extraction, properties, and impacts of humic matter.

This volume uses a molecular approach to bring the reader up to date with research into the structure and properties of these unusual materials. Agricultural and environmental scientists will find its coverage of HS use for soil remediation and enhancement and in water purification as alternatives to conventional methods invaluable.