Petroleum Refinery Process Modeling

A comprehensive review of the theory and practice of the simulation and optimization of the petroleum refining processes Petroleum Refinery Process Modeling offers a thorough review of how to quantitatively model key refinery reaction and fractionation processes. The text introduces the basics of dealing with the thermodynamics and physical property predictions of hydrocarbon components in the context of process modeling. The authors - three experts on the topic - outline the procedures and include the key data required for building reaction and fractionation models with commercial software. The text shows how to filter through the extensive data available at the refinery and using plant data to begin calibrating available models and extend the models to include key fractionation sub-models. It provides a sound and informed basis to understand and exploit plant phenomena to improve yield, consistency, and performance. In addition, the authors offer information on applying models in an overall refinery context through refinery planning based on linear programming. This important resource: -Offers the basic information of thermodynamics and physical property predictions of hydrocarbon components in the context of process modeling -Uses the key concepts of fractionation lumps and physical properties to develop detailed models and workflows for atmospheric (CDU) and vacuum (VDU) distillation units -Discusses modeling FCC, catalytic reforming and hydroprocessing units Written for chemical engineers, process engineers, and engineers for measurement and control, this resource explores the advanced simulation tools and techniques that are available to support experienced and aid new operators and engineers.

A pioneering and comprehensive introduction to the complex subject of integrated refinery process simulation, using many of the tools and techniques currently employed in modern refineries. Adopting a systematic and practical approach, the authors include the theory, case studies and hands-on workshops, explaining how to work with real data. As a result, senior-level undergraduate and graduate students, as well as industrial engineers learn how to develop and use the latest computer models for the predictive modeling and optimization of integrated refinery processes. Additional material is available online providing relevant spreadsheets and simulation files for all the models and examples presented in the book.

Modeling and Simulation of Catalytic Reactors for Petroleum Refining deals with fundamental descriptions of the main conversion processes employed in the petroleum refining industry: catalytic hydrotreating, catalytic reforming, and fluid catalytic cracking. Common approaches for modeling of catalytic reactors for steady-state and dynamic simulations are also described and analyzed. Aspects such as thermodynamics, reaction kinetics, process variables, process scheme, and reactor design are discussed in detail from both research and commercial points of view. Results of simulation with the developed models are compared with those determined at pilot plant scale as well as commercial practice. Kinetics data used in the reactor model are either taken from the literature or obtained under controlled experiments at the laboratory.

The worldwide petroleum industry is facing a dilemma: the production level of heavy petroleum is higher than that of light petroleum. Heavy crude oils possess high amounts of impurities (sulfur, nitrogen, metals, and asphaltenes), as well as a high yield of residue with consequent low production of valuable distillates (gasoline and diesel). These

Besides covering topics like catalytic cracking, hydrocracking, and alkylation, this volume has chapters on waste water treatment and the economics of managing or commissioning the design of a petroleum refinery. Found only in this volume is material on operating a jointly owned and operated refinery. (Over the last decade, the ownership of many refineries has shifted to small companies, from the large, integrated companies. Because of this shift, many refineries are now jointly owned and operated.) Filled with handy process flow diagrams, this volume is the only reference that a chemical engineer or process manager in a petroleum refinery needs for answers to everyday process and operations questions. * Covers the technologies and operations of petroleum refineries * Provides material on operating a jointly owned and operated refinery * Gives readers a comprehensive introduction to petroleum refining, as well as a full reference to engineers in the field