Phenolic Resins A Century Of Progress

The legacy of Leo Hendrik Baekeland and his development of phenol formal- hyde resins are recognized as the cornerstone of the Plastics Industry in the early twentieth century, and phenolic resins continue to ?ourish after a century of robust growth. On July 13, 1907, Baekeland ?led his “heat and pressure” patent related to the processing of phenol formaldehyde resins and identi?ed their unique utility in a plethora of applications. The year 2010 marks the Centennial Year of the prod- tion of phenolic resins by Leo Baekeland. In 1910, Baekeland formed Bakelite GmbH and launched the manufacture of phenolic resins in Erkner in May 1910. In October 1910, General Bakelite began producing resins in Perth Amboy, New Jersey. Lastly, Baekeland collaborated with Dr. Takamine to manufacture phenolic resins in Japan in 1911. These events were instrumental in establishing the Plastics Industry and in tracing the identity to the brilliance of Dr. Leo Baekeland. Phenolic resins remain as a versatile resin system featuring either a stable, thermoplastic novolak composition that cures with a latent source of formaldehyde (hexa) or a heat reactive and perishable resole composition that cures thermally or under acidic or special basic conditions. Phenolic resins are a very large volume resin system with a worldwide volume in excess of 5 million tons/year, and its growth is related to the gross national product (GNP) growth rate globally.

Thermosets such as phenolic thermosets are brittle at room temperature. Thus, in applications where good mechanical properties are required thermosets must be combined with reinforcements to improve these properties. Composites based on thermoset matrices can substitute for steel and concrete in some applications of civil construction structures because of their higher resistance to oxidation than steel and better freeze–thaw resistance than concrete. Furthermore, phenolic composites can be produced with complex shapes, and with careful design, materials can be obtained with high strength and stiffness and excellent impact strength, making these materials alternatives to metals. Construction materials require fire- and high-temperature-resistant components, and moldings and laminates based on phenolics can be utilized due to their resistance to burning and minimal smoke and toxic fumes production. Phenolic composites can positively impact the building and construction industry by improving safety and reducing cost.

Advanced fibre-reinforced polymer (FRP) composites have become essential materials for the building of new structures and for the repair of existing infrastructure. Advanced fibre-reinforced polymer (FRP) composites for structural applications provides an overview of different advanced FRP composites and the use of these materials in a variety of application areas. Part one introduces materials used in the creation of advanced FRP composites including polyester, vinylester and epoxy resins. Part two goes on to explore the processing and fabrication of advanced FRP composites and includes chapters on prepreg processing and filament winding processes. Part three highlights properties of advanced FRP composites and explores how performance can be managed and tested. Applications of advanced FRP composites, including bridge engineering, pipe rehabilitation in the oil and gas industry and sustainable energy production, are discussed in part four. With its distinguished editor and international team of expert contributors, Advanced fibre-reinforced polymer (FRP) composites for structural applications is a technical resource for researchers and engineers using advanced FRP composites, as well as professionals requiring an understanding of the production and properties of advanced FRP composites, and academics interested in this field. Provides an overview of different advanced FRP composites and the use of these materials in a variety of application areas Introduces materials used in the creation of advanced FRP composites including polyester, vinylester and epoxy resins Explores the processing and fabrication of advanced FRP composites and includes chapters on prepreg processing and filament winding processes

The metal casting, uses large amounts of natural resources, energy and metals as well as generates significant amounts of gases and solid wastes, which have an essential influence on the natural environment and work conditions in casting houses. The condition of the further development is the adjustment to the strategy of the sustainable development.This book examines potential solutions to the economic, ecological, and occupational hazards generated by the foundry industry. It focuses on emissions of chemical compounds during the preparation and formation of molding sands, molds pouring with molten metal, molds cooling and castings knocking out. It also addresses the effects of the spent molding sands reclamation process and the influence of spent sands on the environment during their storage. Establishing the most sustainable techniques for limiting the negative impact of foundry processes on the environment is explored in detail. The book will be valuable to academics and industry professionals alike. Describes the mechanisms of hardening and thermal destruction of individual binders in moulding and core sands; Assesses the influence of moulding and core sands technology on the environment; Discusses state of the art moulding and core sand technology.

The book is a comprehensive treatment of the subject covering a wide range of subjects uniquely available in a single source for the first time. A material science approach has been adopted in dealing with wood adhesion and adhesives. The approach of the authors was to bring out hierarchical cellular and porous characteristics of wood with polymeric cell wall structure, along with the associated non-cell wall extractives, which greatly influence the interaction of wood substrate with polymeric adhesives in a very unique manner not existent in the case of other adherends. Environmental aspects, in particular formaldehyde emission from adhesive bonded wood products, has been included. A significant feature of the book is the inclusion of polymeric matrix materials for wood polymer composites.

This new work, Functional Polymeric Composites: Macro to Nanoscales, focuses on new challenges, findings, opportunities, and applications in the area of polymer composites. The chapters, written prominent researchers from academia, industry, and research institutes from around the world, present contemporary research and developments on advanced polymeric materials, including polymer blends, polymer electrolytes, bio-based polymer, polymer nanocomposites, etc. Several chapters also cover the applications of the polymeric systems in current industry development and synthesis and characterization of the products.

This book covers the latest developments in phenolic foams and their applications. Compared with polystyrene and polyurethane foams, phenolic foams are known as third-generation polymeric foams. Phenolic foams exhibit excellent fire-retardant properties, including low flammability, low peak heat release rate, no dripping during combustion, and low toxicity. This book discusses various aspects of phenolic foams including properties, synthesis, fabrication methodologies, and applications. The contents also cover the methods for toughening of phenolic foams to make them more widely applicable. This book is of interest to both academics and industry alike. It is also a useful reference for fire safety regulators and policy-makers looking for new materials and methods for sustainable fire protection.