Principles Polymer Systems Sol Man

Maintaining a balance between depth and breadth, the Sixth Edition of Principles of Polymer Systems continues to present an integrated approach to polymer science and engineering. A classic text in the field, the new edition offers a comprehensive exploration of polymers at a level geared toward upper-level undergraduates and beginning graduate stu

The Fifth Edition of Principles of Polymer Systems has been completely revised and updated. The chemical engineering perspective has been retained and strengthened, and the broad applications of polymers in chemistry and materials science have been addressed. The theoretical basis for various topics has been deepened and strengthened and several new topics are addressed. These changes reflect the rapidly growing recognition by all scientists and engineers of the role polymers play in industry. Electronics and medicine are representative areas that require more than a passing knowledge of macromolecular principles. Both areas receive attention in this edition. The end-of-chapter problems in the book have been completely replaced with the new problems. A solutions manual will be available to qualified instructors.

The concept for a treatise covering selected natural polymer systems was initiated during a national meeting in cell biology in 1978. The challenge to the editor was to organize a book dealing principally but not exclusively with cellulose. A brief background may help to provide the reader with information to understand the reasons for the specific selections within this volume. better During the past decade, we have witnessed significant changes in the sciences as well as the day-to-day life styles of our citizens. It will not be forgotten that during the early seventies, a significant change was to take many Americans by surprise. The oil embargo on The United States caused unexpected shortages of fuels. The long gasoline lines impressed in the minds of Americans that our energy-rich future with non-renewable resources is limited. The modelling of ecosystems, population growth, urban development, etc., have continued to raise our awareness that life on earth, including renewable resources, is indeed fragile. Contrary to popular belief, even wood and wood products are not limitless.

FROM THE PREFACE Almost all polymeric systems are subjected to a flow field at least once along the route between preparation and application. . . . There is also an increased interest in predictive models on phase behavior and suitable techniques for characterizing the structure of these systems when subjected to flow. Multiphase polymeric systems are particularly susceptible to flow, which may cause orientation of species, morphological changes, and phase transitions. All these events may, in turn, affect the end product properties, such as permeability, electrical conductivity, [and] mechanical properties. In processing, escalating needs have evolved for optimization and development of novel and more uniform product properties and increased productivity. In order to arrive at an understanding of processing polymeric systems under elastic flow conditions, it is convenient to analyze the basic physical mechanisms under conditions that enable development of predictive models in conjunction with controlled experimentation. . . . In recent years, the science of rheo-physics has evolved and now involves both advanced theories and experimental techniques. Rheo-physics means the rheological, morphological, and thermodynamic behavior of structured polymer systems during flow. . . . In this monograph, the rheo-optical techniques are . . . emphasized. The book gives an introduction to rheo-physics, including fundamentals of theories, and a representative selection of applications of rheo-optical techniques for analyzing multiphase systems. The chapters contain both practical advice for the new experimenter . . . as well as review material for the experienced scientist.