Carbon Fibre From Lignin

This book presents detailed information on the production and properties of carbon fibers derived from lignin precursors. Focusing on future directions in the carbon fiber industry, it also introduces a novel process for obtaining high-purity lignin, a key aspect in the manufacture of high-quality carbon fiber. Carbon fiber is currently the most preferred lightweight manufacturing material and is rapidly becoming the material of choice for manufacturers around the world. Although more than 80% of commercial carbon fiber is estimated to use PAN (polyacrylonitrile) as a precursor, carbon fiber manufactured from PAN is expensive and therefore its application is limited to high-performance structural materials. Lignin is the second most abundant biopolymer in nature after cellulose and offers a carbon-rich, renewable resource. As a byproduct of the pulp and paper industry and the production of cellulosic ethanol, lignin is also available at low cost, making it an economically attractive alternative to PAN for the production of carbon fibers, as highlighted in this book. The information presented will be of interest to all those involved in the investigation of carbon fiber materials, carbon fiber manufacturers and carbon fiber users.

This book is designed to provide wide understanding of lignin carbon fiber processes, chemistry, mechanisms, and techniques that will help in further development of lignin carbon fiber for automobile, aerospace, marine, and sports equipment applications. Each step in the processing of lignin carbon fibers is presented as a separate chapter so that issues concerning the processes are exhaustively discussed. Basic scientific principles governing each stage of lignin carbon fiber processing, current state of research and mechanisms behind the processes are illustrated for better understanding. This is the first book to address the entire scope of lignin carbon fiber processing including; extraction, quantification, purification, melt processing, stabilization, carbonization, optimization of processes, and characterization. Presents detailed information on the chemistry, processing, principles and properties of bio-sourced lignin for carbon fiber production; Highlights techniques of recovery and properties of lignin from agricultural waste sources; Addresses applications in automobile, aircraft, marine, and sport industries; Provides insight into the lignin complex macromolecular system, the role of lignin chemistry as it relates to carbon fiber production and the evolution of lignin carbon fiber structure during processing.

Over the past four decades, there has been immense progress in every area of lignin science, ranging from the enzymology of lignin biodegradation, to the delignification of wood fiber during pulping and bleaching, to advances in spectroscopy. Lignin and Lignans: Advances in Chemistry captures the developments that have been achieved by world-class

Lignin in Polymer Composites presents the latest information on lignin, a natural polymer derived from renewable resources that has great potential as a reinforcement material in composites because it is non-toxic, inexpensive, available in large amounts, and is starting to be deployed in various materials applications due to its advantages over more traditional oil-based materials. This book reviews the state-of-the-art on the topic and their applications to composites, including thermoplastic, thermosets, rubber, foams, bioplastics, nanocomposites, and lignin-based carbon fiber composites. In addition, the book covers critical assessments on the economics of lignin, including a cost-performance analysis that discusses its strengths and weaknesses as a reinforcement material. Finally, the huge potential applications of lignin in industry are explored with respect to its low cost, recyclable properties, and fully biodegradable composites, and the way they apply to the automotive, construction, and packaging industries. Reviews the state-of-the-art on the topic and their applications to composites, including thermoplastic, thermosets, rubber, foams, bioplastics, nanocomposites, and lignin-based carbon fiber composites Presents the essential processing and properties information for engineers and materials scientists, enabling the use of lignin in composites Provides critical insight into the applications and future trends of lignin-based composites, including advantages, shortcomings, and economics Includes a thorough coverage of extraction, modification, processing, and applications of the material

Carbon fiber is an oft-referenced material that serves as a means to remove mass from large transport infrastructure. Carbon fiber composites, typically plastics reinforced with the carbon fibers, are key materials in the 21st century and have already had a significant impact on reducing CO2 emissions. Though, as with any composite material, the interface where each component meets, in this case the fiber and plastic, is critical to the overall performance. This text summarizes recent efforts to manipulate and optimize the interfacial interaction between these dissimilar materials to improve overall performance.

One of the most significant challenges facing mankind in the twenty-first century is the development of a sustainable global economy. Within the scientific community, this calls for the development of processes and technologies that will allow the sustainable production of materials from renewable natural resources. Plant material, in particular lignin, is one such resource. During the annual production of about 100 million metric tons of chemical wood pulps worldwide, approximately 45 and 2 million metric tons/year of kraft lignin and lignosulfonates, respectively, are also generated. Although lignosulfonates have found many applications outside the pulp and paper industry, the majority of kraft lignin is being used internally as a low-grade fuel for the kraft pulping operation. A surplus of kraft lignin will become available as kraft mills increase their pulp production without expanding the capacity of their recovery boilers that utilize lignin as a fuel. There is a tremendous opportunity and an enormous economic incentive to find better uses of kraft lignin, lignosulfonates and other industriallignins. The pulp and paper industry not only produces an enormous amount of lignins as by products of chemical wood pulps, but it also utilizes about 10 million metric tons of lignin per year as a component of mechanical wood pulps and papers. Mechanical wood pulps, produced in a yield of 90-98% with the retention of lignin, are mainly used to make low-quality, non-permanent papers such as newsprint and telephone directories because of the light-induced photooxidation of lignin and the yellowing of the papers.

Carbon fibre is the most preferred lightweight manufacturing material, and is increasingly becoming the material of choice for manufacturers around the world. Its high tensile strength, low weight and low thermal expansion have opened a world of opportunities. Everyone from elite athletes, to car enthusiasts, to the makers of passenger jets, is moving to carbon fibre. The objective of this Update is to bring together available information on the production, properties, application and future of carbon fibres. This Update will be of interest to those involved in the investigation of carbon fibre, carbon-fibre manufacturers, and users of carbon fibres. A further objective is to review the status of carbon fibre-reinforced polymer (CFRP) recycling operations, focusing on state-of-the-art fibre reclamation and re-manufacturing processes, as well as the commercialisation and potential applications of recycled products. This Update will also be of interest to those involved in the recycling of CFRP and manufacturing of composites from recycled CFRP. Students engaged in the fields of chemistry, material science and polymer science will also find this Update very useful.