Introduction To The High Temperature Oxidation Of Metals

A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This 2006 second edition retains the fundamental theory but incorporates advances made in understanding degradation phenomena. The first half provides an authoritative introduction to the basic principles, covering thermodynamics and mechanisms of high temperature corrosion of metals and alloys. The latter half extends the discussion to oxidation processes in complex systems, from reactions in mixed environments to protective techniques, including coatings and atmosphere control. The authors provide a logical and expert treatment of the subject, producing a revised edition that will be a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.

This text for graduate and post graduate students covers fundamentals of high temperature corrosion and related topics. Early chapters cover the thermodynamics and kinetics of oxidation and defect structure of oxides and diffusion in oxides, and later chapters cover thin and thick layer oxidation, o

The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.

A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This new edition retains the fundamental theory and applies it to reactions in mixed environments and protective techniques. This book is a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.

Metals and alloys rely for their application at high temperature on the formation and retention of oxide scales, which act as a barrier between the metallic substrate and the reactive species in the environment such as 0, S, N, C, Cl, etc. This protection concept requires that the oxide grows slowly, develops a dense, uniform layer, is well adherent, has sufficient ductility to accom modate plastic deformation of the substrate and is resistant to thermal cycling. For many years it has been known that small concentrations of certain "active elements" such as Y and the rare earths, as well as carbon and sulphur, can exercise a significant influence upon the oxidation! corrosion behaviour of high temperature metals and alloys. An increasing number of experimental studies on this topic have been published recently. However no generally accepted understanding with regard to the detailed mechanisms and the way in which alloy composition and structure, temperature and environmental conditions, etc., are interacting has yet been achieved, although many - often controversial - theories and ideas have been presented. It therefore seemed to be an appropriate time to bring together a group of experts to review and evaluate the current state-of-the-art and to discuss various aspects of this important topic.

George Lai's 1990 book, High-Temperature Corrosion of Engineering Alloys, is recognized as authoritative and is frequently consulted and often cited by those in the industry. His new book, almost double in size with seven more chapters, addresses the new concerns, new technologies, and new materials available for those engaged in high-temperature applications. As we strive for energy efficiency, the realm of high-temperature environments is expanding and the need for information on high temperature materials applications was never greater. In addition to extensive expansion on most of the content of the original book, new topics include erosion and erosion-corrosion, low NOx combustion in coal-fired boilers, fluidized bed combustion, and the special demands of waste-to-energy boilers, waste incinerators, and black liquor recovery boilers in the pulp and paper industry. The corrosion induced by liquid metals is discussed and protection options are presented.